Materials

PEEK Bonding and Surface Treatment: What You Must Know

2020-01-10

PEEK is hard to bond — and that is a feature for the mouth, a headache for the lab. You must earn the bond.

Why it resists

PEEK's inert, low-surface-energy surface rejects standard phosphate primers. A direct composite bond fails at the interface within months.

How to make it stick

  1. Silica-coat (e.g., silica sandblasting / 30 µm Al₂O₃ + silica) to create a bondable layer.
  2. Prime with a silica-friendly adhesive (MMA-based, not classic etch).
  3. Mechanically retain — grooves and undercuts beat chemistry alone.
Bond PEEK to composite only after silica treatment; raw PEEK + composite is a future debond.

Machine the frame from our PEEK discs, then surface-treat per the above.

Treatment protocols

MethodEffect
30 µm Al₂O₃ + silicaSilica layer, bondable
PlasmaSurface energy up
Primer MMAWets silica

Make the bond last

  1. Silica-coat, do not just sandblast — grit alone gives no chemical grip.
  2. Use an MMA-based primer; classic phosphoric etch does nothing to PEEK.
  3. Build mechanical retention with grooves; chemistry alone fails.
  4. Test shear on a scrap PEEK tab before the case.

References & Further Reading

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